Gammaxene is:

  1. chlorobenzene
  2. benzyl chloride
  3. bromobenzene
  4. benzenehexachloride

Answer (Detailed Solution Below)

Option 4 : benzenehexachloride
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Detailed Solution

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Explanation:

  • The IUPAC name of Gammexene is benzene hexachloride or, 1,2,3,4,5,6- hexachlorocyclohexane.
  • The trade names are Gammaxene, Lindane, and 666.
  • It is prepared by the addition of chlorine to benzene in the presence of U.V sunlight.

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  • It is used as a pesticide in agriculture.
  • Nine stereomers are possible for this compound. Among these seven meso compounds and two are enantiomers which exist as a racemic mixture.

Hence, Gammaxane is benzene hexachloride.

Important Points

  •  Chlorobenzene is a monohalide of benzene that can be prepared by chlorination of benzene in presence of fecl3 as a catalyst. Its chemical formula is C6H5Cl.

C6H6  + Cl → C6H5Cl + HCl

  • Bromobenzene, C6H5Br, can also be prepared in a similar way.
  • Chloro benzene when treated with oxidizing agents, yields chlorobenzene acid, as the side chain goes oxidation.
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