Given the matrices for C3 and σh below,

the trace of the matrix representing for  is

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CSIR-UGC (NET) Chemical Science: Held on (26 Nov 2020)
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  1. 0
  2. -2
  3. 1
  4. -1

Answer (Detailed Solution Below)

Option 1 : 0
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Detailed Solution

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Concept:-

  • An action that leaves an object looking the same after it has been carried out is called a symmetry operation.
  • The symmetry operations include rotation, reflection, the alternating axis of symmetry, and inversions.
  • A molecule possessing an alternative axis of symmetry (Sn) of n fold represents the rotation of the molecule about the axis  followed by reflection through a plane perpendicular to this axis produces an indistinguishable structure.
  • Sn It can be represented by,

 

  • The trace of a matrix A, designated by tr(A), is the sum of the elements on the main diagonal.
  • If matrix A is represented by the matrix,

then the trace of matrix A is given by,

tr(A)= 1+1-1

=1

Explanation:-

  • The alternative axis of symmetry (Sn) is represented by,

  • Now,  is given by,

  • Thus, trace of the matrix  is given by,
     

Trace of matrix  is,

Conclusion:-

Hence, trace of the matrix representing for  is 0

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