The products formed during the electrolysis of brine are

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  1. Na2SO4, SO2, H2
  2. NaOH, H2, Cl2
  3. NaCl, H2, Cl2
  4. Na2CO3, CO2, H2

Answer (Detailed Solution Below)

Option 2 : NaOH, H2, Cl2
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The correct answer is NaOH, H2, Cl2

Key Points

  • During the electrolysis of brine (aqueous NaCl solution), NaOH, H2, and Cl2 are produced.
  • Chlorine gas (Cl2) is liberated at the anode (oxidation reaction).
  • Hydrogen gas (H2) is liberated at the cathode (reduction reaction).
  • Sodium hydroxide (NaOH) is formed in the solution as a by-product.

Important Points

  • Electrolysis of brine: Brine is a concentrated solution of sodium chloride (NaCl) in water. When subjected to electrolysis, it undergoes decomposition into its components.
  • Chemical equation: 2NaCl(aq) + 2H2O(l) → 2NaOH(aq) + H2(g) + Cl2(g).
  • The process is widely used in the industrial production of chlorine, hydrogen, and sodium hydroxide.
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