Environment friendly refrigerant R 134a is used in the new generation domestic refrigerators. Its chemical formula is

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UPPSC AE Mechanical 2019 Official Paper II (Held on 13 Dec 2020)
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  1. CHCIF2
  2. C2CI3F3
  3. C2CL2F4
  4. C2H2F4

Answer (Detailed Solution Below)

Option 4 : C2H2F4
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Concept:

Nomenclature of refrigerants:

Saturated hydrocarbon refrigerant is given as CmHnFpClq where 2m + 2 = n + p + q must be satisfied. Nomenclature is then written as R - (m - 1)(n + 1)p.

Unsaturated hydrocarbon refrigerant must satisfy 2m = n + p + q and nomenclature is then written as R - 1(m - 1)(n + 1)p.

Inorganic refrigerant uses nomenclature R - (700 + Molecular mass).

Calculation:

Given:

For R-134a, we have

m – 1 = 1 i.e. m = 2.

n + 1 = 3 i.e. n = 2 and p = 4.

It must satisfy this 2m + 2 = n + p + q therefore, we get q = 0.

∴ we get, C2H2F4

Additional Information

C2H2F4 has two structures out of which one is symmetrical and one is asymmetrical the 'a' in 134a stands for asymmetrical structure.

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