Question
Download Solution PDFThe major product formed in the following reaction is
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFConcept:
This reaction proceeds via carbene mechanism followed by rearrangement.
Neutral reaction intermediates having six valance electrons are called carbenes, which are of two types.
singlet:
It is bent in shape, sp2 hybridised, two electrons are paired, less stable.
Triplet:
It can remain in two possible ways
sp2 hybridized, bent in shape
or sp hybridised, linear in shape
There are four methods to synthesize carbene
(i) Thermal decomposition of diazo compounds:
(ii) \(\alpha\)-elimination of HX from haloform:
(iii)\(\alpha\)-elimination of X from RCHX2 in presence of a metal or an organolithium
(iv)Removal of H+ from a cation in the presence of a strong base like NaOH
Explanation:
The mechanism of the reaction is given below.
Conclusion:
Hence the correct answer is option 3.
Last updated on Jun 5, 2025
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