What product will be formed when ethanol at 443K with excess concentrated sulphuric acid is heated? 

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RRB Technician Grade III Official Paper (Held On: 29 Dec, 2024 Shift 2)
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  1. Ethyne and hydrogen 
  2. Ethene and water 
  3. Ethane and water  
  4. Only ethyne 

Answer (Detailed Solution Below)

Option 2 : Ethene and water 
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Detailed Solution

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The correct answer is Ethene and water.

Key Points

  • When ethanol is heated at 443K with excess concentrated sulphuric acid, it undergoes a dehydration reaction.
  • The dehydration of ethanol results in the formation of ethene (C2H4) and water (H2O).
  • Concentrated sulphuric acid acts as a dehydrating agent in this reaction.
  • The chemical equation for this reaction is: C2H5OH → C2H4 + H2O.

Additional Information

  • Dehydration Reaction:
    • A type of chemical reaction that involves the loss of water from the reacting molecule.
    • In organic chemistry, it is commonly used to convert alcohols to alkenes.
  • Role of Sulphuric Acid:
    • Concentrated sulphuric acid (H2SO4) is used as a catalyst and dehydrating agent in the reaction.
    • It helps in the removal of a water molecule from ethanol to form ethene.
  • Ethene (Ethylene):
    • A colorless flammable gas with a faint "sweet and musky" odor.
    • It is the simplest alkene and an important building block in the petrochemical industry.
  • Applications of Ethene:
    • Ethene is widely used in the production of polymers such as polyethylene.
    • It also plays a role in the ripening of fruits and is used as a plant hormone in agriculture.
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